Mechanical, Electrical, and Thermal Performance of Hemp Fiber-Reinforced Elium Biocomposites Modified with Activated Carbon Nanoparticles: Experiment and Simulation

Hemp fiber is increasingly being studied as a renewable reinforcement material for high-performance composites.

In this study, researchers combined hemp fabric with a recyclable thermoplastic resin and activated carbon nanoparticles to examine changes in mechanical strength, electrical behavior and thermal performance.

The results show how hemp-based biocomposites can be engineered for more advanced applications, expanding the plant’s potential beyond traditional fiber products into lightweight, multifunctional materials.

“This research examines the influence of various concentrations (0%, 1%, 1.4% and 1.8% by weight) of activated carbon nanoparticles (AC NPs) on the performance of Elium biocomposites reinforced with hemp fibers.

Unidirectional [0°/0°] laminates with 20% fiber volume fraction were fabricated via hand layup using two layers of 150 GSM hemp fabric and compression molded to achieve 0.9 mm cured thickness.

Quasi-static tensile testing (ASTM D3039, 2 mm/min, 100 mm gauge length) revealed a pronounced non-monotonic relationship between AC NPs loading and mechanical properties, with optimal performance at 1.0 wt.% fillers and catastrophic degradation at 1.8 wt.%. AC NPs filled composites, which were then characterized by their electrical and thermal behavior.

Electrically, it also achieved minimum resistivity (1.62 Ω·m) and maximum conductivity (0.62 S·m-1), in contrast to the elevated resistance (42.5 kΩ) found in samples with a higher filler content.

Thermal analysis showed a slight effect on the degradation of the onset temperature (300 °C) and a higher charring after addition of AC NP. Finite element analysis (FEA) provided a corroboration for these experimental findings, with simulations verification.

Microscopy revealed cohesive fractures in the 1.0 wt.% composite whereas voids and brittle failure were evident in samples with higher loading. Hence, the concentration of 1.0 wt.% AC NP offers the best trade off of mechanical, electrical, and thermal properties.”

https://pubmed.ncbi.nlm.nih.gov/41516850

https://www.mdpi.com/2073-4360/18/1/66


In Situ Synthesis of ZnO Nanoparticles Using Soy Protein Isolate for Sustainable and Multifunctional Finishing of Hemp Fabrics

Hemp fabrics are increasingly being explored as sustainable materials that can be enhanced with added functional properties.

In this study, researchers used soy protein isolate to support the in-situ formation of zinc oxide nanoparticles directly on hemp fabric, creating a more sustainable finishing process.

The treated fabrics showed improved multifunctional performance, highlighting the potential for hemp textiles to be developed for advanced applications beyond conventional clothing and fiber products.

“This study presents an environmentally sustainable finishing approach for hemp fabrics by combining soy protein isolate (SPI) pretreatment with an in situ infrared (IR)-assisted synthesis of zinc oxide nanoparticles (ZnO NPs).

IR heating was employed to reduce energy consumption while promoting efficient nanoparticle formation compared to conventional thermal processing, while SPI acted as a bio-based stabilizer to enable uniform ZnO NP distribution on the fabric surface. Transmission electron microscopy revealed predominantly spherical to polyhedral ZnO NPs with minimal agglomeration, and X-ray diffraction confirmed their characteristic wurtzite crystalline structure. Scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy mapping further verified the homogeneous deposition of ZnO NPs on hemp fibers.

The treated fabrics exhibited multifunctional performance, showing significantly enhanced ultraviolet (UV) protection with a UV protection factor (UPF) of 50+ compared with untreated hemp.

Antibacterial activity against Staphylococcus aureus and Escherichia coli was confirmed by the AATCC TM147 test, while a quantitative AATCC TM100 assessment demonstrated an excellent antibacterial efficiency of 99.99% bacterial reduction against S. aureus. Additionally, the incorporation of 2 wt% SPI significantly improved fabric hydrophilicity and wettability.

Overall, this work demonstrates a green and effective strategy for producing antibacterial and UV-protective hemp textiles.”

https://pubmed.ncbi.nlm.nih.gov/41516899

“This study successfully developed a novel antibacterial finishing process for hemp fabrics by combining SPI pretreatment with an IR-assisted in situ synthesis of ZnO NPs.”

“Consequently, this work provides a generalized and scalable framework for the development of eco-friendly antibacterial and UV-protective textile finishes.”

https://www.mdpi.com/2073-4360/18/1/116


Cannabidiol-Loaded Mucoadhesive PLGA Nanosphere-Chitosan Hydrogel Patch for Oral Therapeutic Applications

Delivering cannabidiol (CBD) directly to tissues inside the mouth could provide a new approach to treating inflammatory oral diseases such as gingivitis and periodontitis.

In this study, researchers developed a mucoadhesive hydrogel patch containing CBD-loaded nanospheres designed to remain attached to oral tissue and gradually release CBD. The formulation demonstrated sustained CBD release, improved mucosal permeability, strong antibacterial activity and reductions in inflammatory markers.

The findings highlight the potential of targeted CBD delivery systems for treating inflammation and supporting healing in the mouth.

“Cannabidiol (CBD), the primary bioactive element of cannabis, has shown promise in alleviating pain and inflammation, although mechanisms in periodontal inflammation are not fully understood.

To improve its limited solubility and mucosal permeability, the developed chitosan-based mucoadhesive hydrogel incorporating CBD-loaded PLGA nanospheres (CPN hydrogel) was characterized by FT-IR, SEM, particle size, rheological, swelling, and diffusion analyses, followed by biological evaluations, including wound-healing and RT-qPCR-based anti-inflammatory assays.

The improved CPN hydrogel had a homogeneous shape, better viscoelastic behavior, and sustained drug release. Over 90% of CBD was released within 96 h, and Franz cell experiments showed improved permeability (124.1 μg/cm2 after 72 h). The gellan gum-based mucosal substrate significantly increased adhesion (1137.33 ± 142.25 s) compared to the control groups.

Antioxidant studies indicated 73.65% DPPH radical scavenging, whereas antibacterial tests showed more than 99% suppression of Staphylococcus aureus. Furthermore, in vitro studies validated its wound healing and the downregulation of the inflammatory cytokines IL-6 and TNF-α.

The results indicate that the CPN-loaded chitosan hydrogel has extended mucosal retention, strong antibacterial activity, and steady release of CBD. This underscores its significant potential as a targeted treatment for inflammatory oral diseases such as gingivitis and periodontitis.”

https://pubmed.ncbi.nlm.nih.gov/41596768

“Cannabidiol (CBD), a non-psychoactive phytocannabinoid from Cannabis sativa with anti-inflammatory, immunomodulatory, and antimicrobial properties, is a promising bioactive compound for oral health applications [9,10,11]. In addition, CBD not only reduces inflammation, but also fights P. gingivalis very well.”

https://www.mdpi.com/1422-0067/27/2/1127


Development of smart/active chitosan/Kapppa-carrageenan films incorporating Aronia anthocyanin and ginger essential oil Pickering emulsion stabilized by hempseed protein nanoparticles

Hempseed protein is finding new uses as a functional ingredient in sustainable food-packaging technologies.

In this study, researchers used hempseed protein nanoparticles to stabilize a ginger essential-oil nanoemulsion incorporated into an edible film designed to both protect food and indicate freshness. The resulting material showed improved antioxidant and antimicrobial activity, stronger barrier properties, and color changes in response to conditions associated with spoilage.

The findings highlight hempseed protein’s potential role in developing bio-based “smart” packaging that can help preserve food while also signaling changes in freshness.

“The present study aimed to develop a multipurpose edible film with active (antioxidant/antimicrobial) and intelligent (food freshness monitoring) capabilities.

A Pickering nanoemulsion containing ginger essential oil (PNGEO) was prepared using hempseed protein as a stabilizer.

The effect of incorporating varying concentrations of PNGEO (0%, 5%, 10%w/v) and Aronia anthocyanin extract (AE) (0%, 4%, 8%w/v) on the physicochemical properties of films were evaluated using RSM and CCD, then optimal samples were identified using the utility function method, and their properties were examined.

The results demonstrated that the PNGEO formed a stable O/W emulsion with a Z-potential of -18.3 mV, a particle size of 108 nm, and PDI of 0.44. The encapsulation efficiencies were 91.72% for PNGEO. The AE exhibited pH-responsive color changes, transitioning from red to green across a pH range of 2-13. Increasing the AE and PNGEO enhanced the films’ water vapor barrier, antioxidant and antimicrobial properties. Elongation at break and tensile strength increased from 19.21% to 45.89% and from 6.25 to 15.97 MPa, respectively.

The pH color changes and sensitivity to ammonia gas confirmed the smart functionality of films. SEM and FTIR revealed minor changes in the chemical structure and strong molecular interactions between the biopolymer matrix and the incorporated components. XRD and DSC analyses indicated an increase in crystallinity index and a slight reduction in thermal stability. Release kinetics studies showed that higher temperatures and GEO content can increase the release rate and D values.

In conclusion, the film containing 8% AE and 10% PNGEO showed the best performance by simultaneously providing improvements in antioxidant/antimicrobial properties and sensitive color response to volatile spoilage compounds, and is introduced as a bio-based system with dual capabilities for maintaining quality and monitoring food freshness.”

https://pubmed.ncbi.nlm.nih.gov/41904862

“A novel active/smart edible film based on chitosan/kappa-carrageenan was developed using a Pickering nanoemulsion containing ginger essential oil and stabilized with hempseed protein and aronia anthocyanin extract to enhance the biopolymer’s properties.”

https://www.sciencedirect.com/science/article/abs/pii/S0308814626009222?via%3Dihub


Green Synthesis and Characterization of Nanographene-MnO Composite Nanoparticles for CO2 Capture: Adsorption Performance, Isotherm Analysis, and Reusability

Cannabis and hemp-derived materials are increasingly being explored in environmental technologies as well as medical and industrial research.

In this study, researchers developed nanographene–manganese oxide composite nanoparticles using a green synthesis approach and evaluated their ability to capture carbon dioxide. The material showed effective CO₂ adsorption, favorable adsorption behavior and reusability across repeated cycles.

The findings highlight the potential of plant-assisted nanomaterials for more sustainable carbon-capture technologies.

“In this study, hybrid composite nanoparticles (MnO-NG/green) containing nanographene (NG) and manganese oxide (MnO) were produced by using an environmentally friendly synthesis approach, and their CO2 adsorption performance was investigated in detail.

The conventional method was used to synthesize MnO-NG composites, which were then compared with MnO-NG/green composites prepared via green synthesis using bioextract from the hemp plant.

The composite nanoparticles were structurally characterized using various analytical methods, including FTIR, XRD, SEM, TEM, EDX, and BET analyses. The surface morphology of the composites obtained through green synthesis demonstrated a more homogeneous and regular distribution of MnO nanoparticles on the NG surface.

BET analysis revealed that the specific surface area of the MnO-NG/green composites was 629 m2/g, with a mean pore diameter of 4.65 nm. CO2 adsorption tests were conducted at 273 and 298 K under 1 bar, and it was determined that the MnO-NG/green composites achieved 5.81 and 4.94 mmol/g CO2 uptake capacities, respectively.

These values were significantly higher than those of NG (2.59-2.07 mmol/g) and conventional MnO-NG (4.43-3.74 mmol/g) composites. Analysis of the adsorption isotherm models indicated that the experimental data were better fitted by the Langmuir model. The calculated isosteric heat of adsorption (Q st, 19.4-24.5 kJ/mol) suggests that the adsorption of CO2 by MnO-NG/green composites predominantly occurs via physisorption. The MnO-NG/green composites demonstrated high structural stability and thermal resistance in five-cycle reusability tests, showing a reuse efficiency of 97%.

This study clearly demonstrates that the production of MnO-NG/green composite nanoparticles via a green synthesis offers a promising approach.”

https://pubmed.ncbi.nlm.nih.gov/42110753

“This study provides a strong demonstration of the successful production of nanographene-manganese oxide (NG-MnO) composite nanoparticles via an environmentally friendly green synthesis method and of the use of this structure as a high-performance adsorbent for CO2 capture applications. Superior properties were exhibited by MnO-NG/green composites produced using bioextracts from the hemp plant”

“In conclusion, the achievement of sustainable material production through a green synthesis approach with low environmental impact is not the study’s only accomplishment. The development of a high-performance, reusable, and environmentally friendly adsorbent that can contribute to the reduction of CO2 emissions is another. The resulting MnO-NG/green nanocomposites could be used in many different ways, from in the lab to in industry, which makes them a good choice for next-generation adsorbents in carbon capture technologies.”

https://pubs.acs.org/acsodf/article/11/17/25730/5145806/Green-Synthesis-and-Characterization-of


Phytochemistry-Guided Green Synthesis of Antimicrobial Silver Nanoparticles from Cannabis sativa Chemovars

Cannabis sativa contains a diverse mixture of phytochemicals that may also be useful in the development of antimicrobial materials.

In this study, researchers used extracts from different cannabis chemovars to guide the green synthesis of silver nanoparticles and examined how differences in plant chemistry influenced nanoparticle formation and biological activity.

The resulting nanoparticles showed antimicrobial potential, highlighting how cannabis-derived compounds may serve as natural reducing and stabilizing agents in the development of new bioactive nanomaterials.

“The phytochemical variability in Cannabis sativa L. chemovars represents an underexplored factor in environmentally sustainable nanomaterial production.

In this study, three distinct chemovars, (i) High-Δ9-Tetrahydrocannabinol (THC) (89% THC), (ii) Balanced (60% Cannabidiol (CBD)), and (iii) High-CBD (89% CBD), were comparatively evaluated to determine their suitability for the green synthesis of silver nanoparticles (AgNPs).

Ethanolic inflorescence extracts were used to recover bioactive secondary metabolites; among them, the High-CBD extract exhibited the highest total phenolic (3.34 mg gallic acid equivalent/g) and flavonoid (29.49 mg quercetine equivalent/g) contents, together with superior antioxidant capacity (53.16% 2,2-diphenyl-1-picrylhydrazyl free radical (DPPH) inhibition), indicating enhanced redox potential for nanoparticle formation. The terpene profile of High-CBD showed a dominance of myrcene (21.4%), contributing to the stabilization of the system.

Using the High-CBD extract, predominantly spherical nanoparticles of 5 ± 0.9 nm were synthesized and confirmed by UV-vis, EDS, and TEM. The biogenic AgNPs demonstrated significant dose-dependent antibacterial activity, with minimum bactericidal concentration (MBC) of 1.0 mg/mL against Staphylococcus aureus and 4.5 mg/mL against Escherichia coli.

These findings highlight the critical role of chemovar-dependent phytochemical composition and support a phytochemistry-guided approach for developing silver nanoparticles with potential biomedical applications.”

https://pubmed.ncbi.nlm.nih.gov/42123299

“This approach pursues to emphasize the relevance of full-spectrum compositions in cannabis extracts, particularly considering the reported ‘entourage effect’, where synergistic interactions among metabolites may enhance biological activity.”

“As a recognized medicinal plant, utilizing these inflorescence-derived compounds imparts an intrinsic therapeutic ‘added value’ to the nanoparticles.”

“By leveraging the synergistic potential between the plant’s bioactive constituents … and the antimicrobial silver core, this method offers an enhanced potential for biomedical applications compared to traditional chemical synthesis.”

“The successful synthesis of small, stable, and biologically active silver nanoparticles using the High-CBD extract underscores the potential of phytochemistry-guided strategies in advancing green nanotechnology for biomedical applications.”

https://www.mdpi.com/1422-0067/27/9/3713


Antimicrobial Agents in Fibrous Materials: A Comprehensive Review of Natural, Inorganic, and Organic Systems

Fibrous materials are increasingly being engineered to do more than provide structure—they can also be designed to resist microbial growth.

This review examines natural, inorganic and organic antimicrobial agents used in fibers and textiles, including plant-derived materials such as hemp. It explores how these agents are incorporated into fibrous systems and how they may help create surfaces with antibacterial and other protective properties.

The review highlights the growing role of bio-based fibers and antimicrobial technologies in developing safer, more functional materials.

“The escalating threat of antimicrobial resistance has spurred extensive research into antimicrobial fibers.

While numerous reviews have comprehensively cataloged the classification and mechanisms of natural, inorganic, and organic antimicrobial agents, a critical gap remains: few have systematically evaluated the engineering strategies that translate intrinsic biocidal activity into durable, real-world fiber performance.

This review addresses this gap by shifting focus from encyclopedic enumeration to a problem-oriented critical assessment of performance optimization strategies. We examine recent advances in natural fibers (bamboo, hemp, chitosan, jute) and synthetic fibers modified with antimicrobial agents, with emphasis on three core challenges-poor wash durability of natural agents, aggregation and leaching of inorganic nanoparticles (e.g., Ag, ZnO, MOFs), and structural limitations of organic agents (e.g., QACs, QPSs, N-halamines, PHMB). Key optimization routes, including covalent grafting, microstructural control (e.g., triaxial microfluidic spinning), organic-inorganic hybridization, and rechargeable N-halamine systems, are critically assessed for their effectiveness in enhancing washing resistance, stability, and antimicrobial synergy.

Based on this comparative synthesis, we identify future directions-smart-responsive systems, sustainable processing pathways, and standardized evaluation protocols-to guide the rational design of next-generation high-performance antimicrobial fibers.”

https://pubmed.ncbi.nlm.nih.gov/42513717

“Zhao and colleagues successfully converted seed-type hemp into regenerated cellulosic fibers through sequential degumming, pulping, and spinning processes”

“The resultant fibers exhibited significant antimicrobial effectiveness”

“The observed antimicrobial effects are primarily attributed to cannabinoids and their derivatives.”

“As global healthcare and sustainability challenges change, antimicrobial fibers are set to be crucial components in innovative solutions for public health protection and advanced material applications.”

https://www.mdpi.com/1996-1944/19/14/2980


Collective weak interactions of formic acid with hemp protein: Mechanism and application in Pickering emulsion stabilization

Hemp protein is being explored as a functional ingredient in advanced food and material systems, but its performance depends heavily on how it interacts with other molecules.

In this study, researchers examined how formic acid interacts with hemp protein and how those interactions influence the protein’s structure, solubility and ability to stabilize Pickering emulsions.

The findings help explain how hemp protein can be modified to improve emulsion stability, supporting its potential use in food, pharmaceutical and other formulation technologies.

“Anti-solvent precipitation using formic acid (FA, 0-98%, v/v) was developed to fabricate hemp protein nanoparticles (HPNs) for Pickering emulsion stabilization.

FA ≥10% (v/v) increased hemp protein solubility from 38.0% to 86.9% by solubilizing storage globulins, yielding HPNs with tunable sizes (100-780 nm), high ζ-potentials (>30 mV), and adjustable contact angles (57.7°-126.6°).

HPNs prepared at 40% FA exhibited optimal interfacial properties, including the lowest interfacial tension and highest emulsifying activity index (∼1800 m2/g), forming Pickering emulsions with 3-week stability and solid-like rheology.

Spectroscopic analysis revealed concentration-dependent conformational changes: invariant Raman spectra confirmed intact primary bonds, while fluorescence and UV-vis indicated initial unfolding (10-40%) followed by refolding (50-98%), and FT-IR showed that β-sheet content peaked at 61% (40% FA), which correlated with optimal interfacial performance.

Molecular dynamics simulations elucidated a dynamic “besieging effect” where numerous FA molecules collectively disrupted edestin’s hydrogen-bond network via weak interactions (binding energy -3.1 kcal/mol), inducing transient conformational expansion.

This work demonstrates the feasibility of FA as a solvent system for hemp protein nanoparticle fabrication and provides mechanistic insights into unconventional protein-solvent interactions, offering a foundation for future food-grade applications.”

https://pubmed.ncbi.nlm.nih.gov/42637338

“Tunable hemp protein nanoparticles with adjustable wettability are fabricated for Pickering emulsion stabilization.”

https://www.sciencedirect.com/science/article/abs/pii/S096399692601865X?via%3Dihub


Rethinking Punitive Responses to Underage Marijuana Use in the Era of Legalization: Insights from an Online Survey

As cannabis legalization expands, questions remain about how society should respond when minors possess, use or attempt to purchase marijuana.

This study surveyed more than 1,500 U.S. registered voters about penalties and interventions for underage cannabis-related behavior. Respondents generally showed stronger support for parental notification, community service and drug education than for jail time, while support varied depending on the specific offense.

The findings provide a snapshot of public attitudes toward balancing accountability, prevention and punishment in the legalization era.

Background: As adult nonmedical marijuana use becomes legal in many U.S. states, policymakers have adopted a range of responses to underage marijuana-related behaviors, often emphasizing punitive consequences. The extent to which these approaches align with public preferences remains unclear.

Methods: Data were drawn from an online survey of 1502 U.S. registered voters recruited from a national opt-in online panel. Analyses assessed support for a range of consequences for underage marijuana-related behaviors (i.e., possession, use, sale, and use of false identification), with selected bivariate comparisons across demographic groups.

Results: Respondents supported penalties for using false identification (89%) and selling marijuana (84%); fewer supported penalties for possession (59%) or use (57%). For attempted purchases, parental notification (79%), community service (64%), and drug education (58%) were more commonly endorsed than jail time (18%). Several differences by age, sex, race/ethnicity, and parent status were observed.

Conclusions: Respondents generally expressed greater support for parental notification, community service, and education as a response to underage violations of marijuana laws than for punitive responses. Policies that emphasize supportive, health-oriented responses, alongside stronger adult and industry accountability, may be more consistent with public attitudes and more effective than punitive responses in advancing youth protection goals in legalized contexts.”

https://pubmed.ncbi.nlm.nih.gov/42640046

https://www.tandfonline.com/doi/full/10.1080/10826084.2026.2722321

Effects of stir-fried Hemp (Cannabis sativa L.) seed polysaccharides on blood deficiency syndrome in rats based on metabolomics and gut microbiota

Hemp seeds contain more than protein and fatty acids—they also provide complex polysaccharides that may have biological effects.

In this animal study, researchers examined polysaccharides from stir-fried Cannabis sativa seeds in rats with blood deficiency syndrome. Using metabolomics and gut microbiota analysis, they found changes in metabolic pathways and intestinal microbial communities associated with the treatment.

The findings suggest that hemp seed polysaccharides may influence blood-related physiological processes through interactions between metabolism and the gut microbiome.

“This study evaluated the therapeutic potential of raw hemp seed polysaccharides (HSP) and stir-fried hemp seed polysaccharides (FHSP) in a rat model of blood-deficiency syndrome induced by cyclophosphamide and acetylphenylhydrazine.

Both HSP and FHSP are acidic heteropolysaccharides primarily composed of arabinose, galacturonic acid, and galactose, but differ in molecular weight, monosaccharide ratios, and microstructure. Methylation and GC-MS analyses indicated that HSP and FHSP shared similar major glycosidic linkage types, predominantly including →5)-Araf-(1→, Galp-(1→, →4)-GalAp-(1→, and →6)-Galp-(1→, but differed in their relative molar proportions.

In vivo experiments showed that both HSP and FHSP significantly improved hematological parameters (RBC, WBC, HGB, and HCT), regulated cytokine levels (EPO, G-CSF, TNF-α, and IL-6), and alleviated splenic damage. Compared with HSP, FHSP produced more pronounced improvements in several evaluated indicators under the present experimental conditions.

Mechanistic analyses suggested that the beneficial effects of FHSP may be associated with the JAK1-STAT1 signaling pathway, amelioration of splenic metabolic dysfunction involving arachidonic acid, glutathione, riboflavin, and arginine and proline metabolism, and modulation of the gut microbial community.

These findings suggest that FHSP has potential for alleviating blood deficiency syndrome and provide new insights into the further development and application of hemp seed polysaccharides.”

https://pubmed.ncbi.nlm.nih.gov/42629028

https://www.sciencedirect.com/science/article/abs/pii/S0963996926014754?via%3Dihub